Centellian24
Madeca Daily Repair Ampoule 50ml
A lactobacillus-fermented centella asiatica filtrate is the first ingredient of this 50 ml Centellian24 ampoule, ahead of water in seventh, with niacinamide fifth and centella returning down the list as leaf extract, oil, amino acid and hydrolysed protein. Korean-market formula.
No reviews yet50ml
$57.98 per 100 ml
- Korean-market formula
- Ships from California or direct from Korea
- Korean barcode and batch code intact
- Suited to
- Dry skinCompromised barrierDehydrated skinSensitive skin
- Helps with
- Shoppers looking for Niacinamide in an ampouleRoutines that want Niacinamide and Adenosine in one stepFilling the ampoule step with a Korean-market formulaAnyone who wants the Niacinamide ampoule sold on Korean shelves
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- 30-day returns
- Free US shipping on orders of $100 or more
- Tracked delivery to your door
How it works
The Madeca Daily Repair Ampoule is a 50ml ampoule, used after toner and before moisturizer, morning and evening. The active it is built around is Niacinamide, named fifth on its own ingredient list. The same list carries Adenosine, Asiaticoside and Madecassic Acid, so the active is not the only thing on it worth naming. How much of the Niacinamide stays on the skin, and for how long, is decided by the ampoule format rather than by the list alone. This is the Original Korean Formula, the ampoule Centellian24 sells in Korea, Niacinamide and all.
Key benefits
- Niacinamide, the active this ampoule is built around
- Adenosine, Asiaticoside, Madecassic Acid and Asiatic Acid on the same list, actives
- Protease and Tetrahydropiperine further down the same list
- Lactobacillus Ferment and Phloretin further down the same list
- Niacinamide named fifth on the manufacturer list printed on this page
- Sourced for the Korean market, not a US-shelf reformulation of this ampoule
Inside the formula
Inside the formula
Centellian24 Madeca Daily Repair Ampoule 50ml
Where does this ampoule go in my routine?
After toner and before moisturizer, morning and evening. Anything thinner than an ampoule goes on before it, and anything richer goes on after. If you are adding it to a routine you already like, give it a week on its own first, so what you see is the Niacinamide and not three changes at once.
Is this the Korean-market ampoule or a US version?
The Korean-market one, Niacinamide and all. We match this ampoule to its Korean barcode before it reaches the shelf, which is the check that tells you which market release you are holding.
What else is on the list besides Niacinamide?
Adenosine, Asiaticoside and Madecassic Acid. The order they are printed in on this ampoule's panel is the order on the box, so you can see where Niacinamide sits relative to them. Further down the same panel: Asiatic Acid, Protease and Tetrahydropiperine.
Not on the ingredient list below: fragrance or parfum, denatured or SD alcohol, essential oils, silicones, parabens, sulfate surfactants, mineral oil or petrolatum and added color.
Full INCI (50): Lactobacillus/Centella Asiatica Extract Ferment Filtrate, Propanediol, Methylpropanediol, 1,2-Hexanediol, Niacinamide, Glycerin, Water, Centella Asiatica Leaf Extract, Panthenol, Laminaria Japonica Extract, Eclipta Prostrata Leaf Extract, Centella Asiatica Extract, Curcuma Longa (Turmeric) Root Extract, Glycine Soja (Soybean) Seed Extract, Sodium Hyaluronate, Hydrogenated Lecithin, Olea Europaea (Olive) Fruit Oil, Centella Asiatica Oil, Butylene Glycol, Sodium Polyacryloyldimethyl Taurate, Glycyrrhetinic Acid, Carbomer, Tromethamine, Ethoxydiglycol, Adenosine, Fructooligosaccharides, Lactobacillus Ferment, Disodium EDTA, Beta-Glucan, Sodium Polyacrylate, PVM/MA Copolymer, Hydrolyzed Hyaluronic Acid, Octyldodecanol, Asiaticoside, Madecassic Acid, Glycolipids, Centella Asiatica Amino Acid, Hydrolyzed Centella Asiatica Protein, Asiatic Acid, C12-13 Pareth-9, Protease, Ectoin, Ceramide NP, Arginine, Ammonium Acryloyldimethyltaurate/VP Copolymer, Tetrahydropiperine, Phloretin, Phytosterols, Phytosphingosine, Ethylhexylglycerin
Ingredient list read from inkeedecoder.com on 18 August 2026.
48 of 50 explained
- Lactobacillus/Centella Asiatica Extract Ferment Filtrate ferment
- This is centella extract fermented by lactobacillus and filtered. Fermenting it adds lactic acid and amino acids to what the centella already carries.
- Propanediol humectant
- Propanediol is a plant-derived glycol used in place of propylene glycol. It hydrates, carries actives into solution, and gives a lighter, less sticky slip than glycerin at the same strength.
- Methylpropanediol humectant
- Methylpropanediol is a small glycol used to hydrate and to help water-soluble actives penetrate the outer layer of skin more evenly. It leaves almost no tack, which suits watery textures.
- 1,2-Hexanediol humectant
- 1,2-Hexanediol is a glycol used for two reasons: it holds water like glycerin, and it makes a formula harder for microbes to live in, so less traditional preservative is needed. Korean formulas use it heavily for that second reason.
- Niacinamide active
- Niacinamide is vitamin B3, and it is the most studied active in Korean formulation. It is used at roughly 2 to 5 percent for the look of uneven tone and visible pores, and it is water soluble, stable and comfortable beside almost every other active, which is why it turns up in so many lists.
- Glycerin humectant
- Glycerin is the most used humectant in skincare. It draws water into the outer layer of skin and holds it there, and it is one of the very few ingredients whose hydrating effect is settled science rather than marketing. Higher amounts feel tacky, which is why it is usually blended.
- Water solvent
- Water is the base almost every serum, toner and cream is built on. It dissolves the water-loving ingredients and sets how light the finished texture feels. On an INCI list it is usually first, which only means it is the largest single ingredient by weight.
- Centella Asiatica Leaf Extract plant extract
- Centella Asiatica is the plant behind the whole cica category, sold as gotu kola or Madagascar centella. Its extract is the anchor of Korean formulas built for easily reddened skin, and its work is done by four triterpenes: asiaticoside, madecassoside, asiatic acid and madecassic acid.
- Panthenol humectant
- Panthenol is pro-vitamin B5: skin converts it to pantothenic acid. It is a humectant that holds water and leaves skin feeling soft and less tight, and it is one of the ingredients formulators reach for when a formula also contains something harsh.
- Laminaria Japonica Extract plant extract
- Laminaria Japonica is kombu kelp. Its extract carries alginates, minerals and iodine, and it is used as a hydrating, mineral-rich ingredient.
- Eclipta Prostrata Leaf Extract plant extract
- Eclipta Prostrata is false daisy, long used in Ayurvedic and East Asian practice. Its extract is used as a conditioning plant extract, most often in scalp and hair formulas.
- Curcuma Longa (Turmeric) Root Extract plant extract
- Turmeric Root Extract carries curcuminoids, well studied plant antioxidants. It is used for the look of dullness and uneven tone, and it tints a formula faintly yellow.
36 more explained
- Glycine Soja (Soybean) Seed Extract plant extract
- Soybean Seed Extract carries isoflavones, plant sterols and soy proteins. It is used as a conditioning antioxidant extract.
- Sodium Hyaluronate humectant
- Sodium Hyaluronate is the salt of hyaluronic acid, and it is what most products labelled hyaluronic actually contain. The salt dissolves more readily and the molecule is smaller, so it sits in the outer layer of skin rather than only on top of it.
- Hydrogenated Lecithin emulsifier
- Hydrogenated Lecithin is lecithin with its unsaturated bonds filled in, which makes it far more stable. It emulsifies and is the standard shell for the liposomes that carry actives into the outer layer of skin.
- Olea Europaea (Olive) Fruit Oil emollient
- Olive Fruit Oil is high in oleic acid and plant sterols. It is a rich emollient that suits dry skin and is heavy enough that blemish-prone skin often does not get on with it.
- Centella Asiatica Oil plant extract
- The oil-soluble fraction of centella, carried in a plant oil. It brings the fat-soluble part of the plant that a water extract leaves behind.
- Butylene Glycol humectant
- Butylene Glycol is a small glycol that does two jobs at once: it holds water in the top layer of skin and it dissolves plant extracts and actives that plain water cannot. It also thins a formula, which is why watery Korean essences lean on it.
- Sodium Polyacryloyldimethyl Taurate thickener
- Sodium Polyacryloyldimethyl Taurate is a polymer thickener that holds a gel stable even with a lot of salt or acid in the formula.
- Carbomer thickener
- Carbomer is a synthetic polymer that only gels once a base neutralises it, which is why arginine or tromethamine sits nearby on the list. It gives the clear, non-stringy gel texture a xanthan formula cannot reach.
- Tromethamine pH adjuster
- Tromethamine neutralises acidic thickeners such as carbomer so they gel, and holds a formula near skin-friendly pH. It is used at a fraction of a percent.
- Ethoxydiglycol solvent
- Ethoxydiglycol is a solvent that keeps stubborn actives in solution, most often vitamin C or an acid, and helps them spread evenly instead of settling out.
- Adenosine active
- Adenosine is a nucleoside that Korea's own cosmetic authority recognises as a wrinkle-care functional ingredient, which is why it appears on so many Korean lists at a low level. It is used for the look of fine lines and is stable and well tolerated.
- Fructooligosaccharides humectant
- Fructooligosaccharides are short fructose chains used as humectants and as food for the skin's own resident microbes.
- Lactobacillus Ferment ferment
- Lactobacillus Ferment is the liquid left after lactobacillus bacteria have fermented a plant or milk substrate. It carries the small molecules the fermentation produced, including lactic acid and amino acids, and is used for the look of dull, uneven skin.
- Disodium EDTA chelator
- EDTA is a chelator: it locks up trace metal ions from water and packaging that would otherwise turn a formula cloudy, off-colour or rancid. It does nothing to skin and appears at a fraction of a percent.
- Beta-Glucan polysaccharide
- Beta-Glucan is a polysaccharide from oats or yeast. It holds a large amount of water, forms a soothing film, and is one of the ingredients formulators reach for in products aimed at reactive skin.
- Sodium Polyacrylate thickener
- Sodium Polyacrylate is a polymer that absorbs many times its weight in water. It thickens a formula and holds water in a gel against the skin.
- PVM/MA Copolymer film former
- PVM/MA Copolymer is a film-forming polymer used to hold a formula in place and, in a mask, to give the peel-off film its strength.
- Hydrolyzed Hyaluronic Acid humectant
- Hydrolyzed Hyaluronic Acid is hyaluronic acid cut into much shorter fragments. The smaller the fragment, the further into the outer layer it can settle, which is why serums stack several sizes together instead of using one.
- Octyldodecanol emollient
- Octyldodecanol is a branched fatty alcohol used as an emollient and as a solvent for pigments and mineral powders. It thickens slightly and leaves a soft finish.
- Asiaticoside active
- Asiaticoside is one of the four active triterpenes isolated from centella and the most studied of them. Korean formulas name it separately when they want to show which fraction of the plant they standardised.
- Madecassic Acid active
- Madecassic Acid is the fourth centella triterpene. A list that names all four is telling you the extract was standardised rather than simply pressed, which is the difference between a cica claim and a cica formula.
- Glycolipids barrier lipid
- Glycolipids are lipids joined to a sugar. In a formula they work partly as barrier lipids and partly as mild emulsifiers, holding oil and water together.
- Centella Asiatica Amino Acid amino acid
- The amino acid fraction of centella asiatica, the plant Korean formulas call cica. It is a hydrating, conditioning fraction rather than the whole extract.
- Hydrolyzed Centella Asiatica Protein protein
- The protein fraction of centella asiatica, cut into fragments small enough to dissolve. It is a plant protein used as a humectant.
- Asiatic Acid active
- Asiatic Acid is the third of centella's four triterpenes and the aglycone form, meaning it has no attached sugar. It is oil soluble, so it turns up in cica creams and balms more than in watery layers.
- C12-13 Pareth-9 surfactant
- An ethoxylated fatty alcohol used as a mild surfactant and solubiliser, most often so an oil-based makeup remover will rinse away with water.
- Protease active
- Protease is an enzyme that breaks down protein. In a cleanser or peel it loosens the protein bonds holding dead surface cells together, which is a gentler route to smoothness than an acid or a scrub.
- Ectoin humectant
- Ectoin is a small molecule that microbes in salt flats and hot springs make to survive extreme conditions. In skincare it holds water tightly around itself, which is why it appears in formulas aimed at reactive, easily dehydrated skin.
- Ceramide NP barrier lipid
- Ceramide NP is the most used cosmetic ceramide, the same class of lipid that makes up roughly half the mortar between cells in the outer layer of skin. Added to a cream it slots into that structure, which is why ceramide formulas feel less leaky rather than merely greasy.
- Arginine amino acid
- Arginine is an amino acid that does two jobs here: it holds water in the outer layer of skin, and it neutralises acidic gelling agents, which is why it often stands in for a synthetic pH adjuster.
- Ammonium Acryloyldimethyltaurate/VP Copolymer thickener
- This is a synthetic thickener that gels quickly and holds an emulsion stable across a wide pH range. It gives a light, non-tacky body.
- Tetrahydropiperine active
- Tetrahydropiperine is a modified form of piperine, the pungent compound in black pepper. It is used in traces to help other actives spread and sink in more evenly.
- Phloretin antioxidant
- Phloretin is a flavonoid from apple and pear trees. It is used as an antioxidant and is often paired with vitamin C and ferulic acid.
- Phytosterols emollient
- Phytosterols are plant sterols, structurally close to the cholesterol in skin's own lipid layer. They soften skin and help the oil phase of a formula hold together.
- Phytosphingosine barrier lipid
- Phytosphingosine is the backbone every ceramide is built on, and skin uses it in its own lipid layer. In a formula it works with ceramides and cholesterol and also keeps the product stable against microbes.
- Ethylhexylglycerin preservative booster
- Ethylhexylglycerin softens skin and boosts a preservative system, which is why it is nearly always sitting beside phenoxyethanol or 1,2-hexanediol. It also cuts down the odour bacteria produce, so it turns up in deodorising products.
- Market
- Korean market, the version sold in Korea
- EAN (barcode)
- 8806109182768
- Made in
- Republic of Korea
- Volume
- 50ml
- Category
- Serum & Ampoule
- Actives
- Adenosine, Beta-Glucan, Centella Asiatica, Ceramide NP, Ectoin, Hyaluronic Acid, Niacinamide, Panthenol, Sodium Hyaluronate
- Ships from
- California or Korea
Orders ship from California or direct from Korea with tracked delivery to your door, and both routes carry the same Korean-market release. Shipping is free on orders of $100 or more. Returns are accepted for 30 days, by mail.
We split shipments free, so one out-of-stock item never holds up the rest of your order.
Where this unit came from
- 1Seoul
Bought as Korean-market stock - 2Barcode
Listed against the Korean barcode on its box - 3California or Korea
Ships to you from either, as the same Korean-market release
We stock the version of a formula that is sold in Korea, not the release a brand prepares for another market under the same name. The barcode in the specification above is the Korean-market one and it is printed on the box you receive.
Every unit keeps its original barcode and batch code intact, so the unit in your hands can be checked against the brand’s own records.
Every order ships from California or direct from Korea, and returns run for 30 days.
Every claim on this page traces to the unit in the box, the barcode, the batch code and the price you can read for yourself.
How to use
- Use it after toner and before moisturizer, morning and evening.
- A few drops pressed over face and neck while the skin is still damp.
- Let it settle for a moment, then follow with a cream rather than leaving it bare.
- Twice a day, every day. It is a routine step rather than something to reach for on bad days.
Worth knowing
- Patch test this ampoule on a small area and wait a day before using it more widely, especially with Niacinamide on the list.
- Introduce this ampoule on its own for the first week, so anything your skin does is traceable to the Niacinamide rather than to three changes at once.
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Centellian24 Madeca Daily Repair Ampoule 50ml
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Centellian24, Korean-market original
Centella ferment ampoule, 50 ml, with Niacinamide, Panthenol and Beta-Glucan.
Verify your unit when it arrives
Verify your unit when it arrives
Korean-market stock with the original barcode and batch code intact, exactly as it left Korea.
On the unit itself
- The Korean-market barcode, unaltered from the retail package.
- The manufacturer’s batch code, exactly as the maker printed it.
정품Genuine article, Korean-market stock
What professionals say
What professionals say
What skin-care professionals say about skin care, quoted from the medical sources linked beside each.
Your skin barrier is basically your outer layer of the skin.
Melissa Piliang, MDDermatologist, Cleveland Clinic Pretty much every step of a Korean skin care routine is going to have some component of hydration.
Alok Vij, MDDermatologist, Cleveland Clinic
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